Gas laws.

Gas laws

For all practical purposes, liquids used in hydraulic systems can be considered incompressible and insensitive to changes in temperature (provided the temperature remains within some quite broad limits). The gas in a pneumatic system is very sensitive to changes in pressure and temperature, and its behaviour is determined by the gas laws described below.

In the following expressions it is important to note that pressures are given in absolute, not gauge, terms and temperatures are given in absolute degrees Kelvin, not in degrees Celsius. If we discuss, say, a litre of air at atmospheric pressure and 20°C being com­ pressed to three atmospheres gauge pressure, its original pressure was one atmosphere, its original temperature was 293 K and its final pressure is four atmospheres absolute.

Pressure and volume are related by Boyle’s law. In Figure 1.24 we have a volume of gas V 1 at pressure P1 (in absolute units,

Fundamental principles-0029

remember). This gas is compressed to volume V2, which will result in a rise of pressure to P2, where:


provided the temperature of the gas does not change during the compression. A reduction of pressure similarly leads to an increase in volume.

In practice, compression of a gas is always accompanied by a rise in temperature (as is commonly noticed when pumping up a bicycletyre) and a reduction in pressure produces a temperature fall (the principle of refrigeration). For expression 1.17 to apply, the gas must be allowed to return to its original temperature.

Fundamental principles-0030

In Figure 1.25, on the other hand, the temperature of a fixed volume of gas is controlled by a heater. A rise in temperature from T1 to T2 results in an increase in pressure from P1 to P2, where:


Again it should be remembered pressure and temperature are in absolute terms. Although expression 1.18 gives the change in pres­sure resulting from a change in temperature, it also applies to changes of temperature resulting from a change in pressure provided no heat is lost from the system. In a pneumatic air compressor, the temperature of the outgoing compressed air is considerably ele­vated by the increase in pressure, resulting in the need for the com­pressor to be followed by an air cooler.

Expressions 1.17 and 1.18 are combined to give the general gas law:


where P1, V 1, T1 are initial conditions and P2, V2, T2 are final conditions. As before, expression 1.19 assumes no heat is lost to, or gained from, the environment.

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